During evening Sandhyavandanam, arghyam is offered while the sun is still present and upasthAnam is performed after the rise of nakshatra-s; it seems the query is asking that when one chant 108 Gayatri mantra-s on all other days since one is allowed to chant only 10 on Pradosham, must we wait for nakshatra ArOhanam for upasthAnam; generally, elders after offering arghyam at the appropriate time, chant Gayatri mantra for 10 times and wait for upasthAnam time; if not possible, is not wrong if the offering of arghyam and performance of upasthAnam are done with a slight deviation in timing; even on Pradosham days, Sandhyavandanam must be performed on time.

