As your elder brother has attained Paramapadam, there is nothing that you can do for your parents; he was the kartA. The performance of rites ends with him and no shraddham need to be performed.
As your elder brother have no other relations who can perform his shraddham, as his siblings you can perform shraddham; qualified males can perform the shraddham by accepting kaippul (darbha grass) from the sisters (females).
For a spinster without parents, last rites can be performed by her siblings. If none are available, others can perform her rites.